Firstly, open the sig/image you would like the border to be added to:

Then create a new layer (
control + shift + alt + N), and select the
POLYGONAL LASSO TOOL:

Hold
Shift and use the polygonal Lasso tool to outline where you want your border to be, and create various effects.
Once you have created your border, click
SELECT>>INVERSE, then press
control + back space., and press
control + I to choose either black or white (can be changed to any colour later)

Now you can edit the colouring (
control + U) and add effects (
right click>>Blending options)
You may also use the Polygonal Lasso Tool to create additional patterns.

NOTE: This can create absolutely any style of border, the border I created was extremely simple and completed in 30 seconds.